06.05.2021

Whats the constant propionality

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09.07.2023, solved by verified expert
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3/2

Explanation:

find where the line hits perfectly on a corner and divide the x by the y, in this case one of the options is 6 divided 4 which is 1.5 (3/2)

Whats the constant propionality, №18011190, 06.05.2021 13:45
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Mathematics
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3/2

Explanation:

find where the line hits perfectly on a corner and divide the x by the y, in this case one of the options is 6 divided 4 which is 1.5 (3/2)

Whats the constant propionality
Chemistry
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P Answered by Master

When comparing propionic acid (CH₃CH₂COOH) and sodium propionate (CH₃CH₂COONa), the one that is more soluble in water sodium propionate.

When comparing cyclohexane (C6H12) and glucose (C6H12O6), the one that is more soluble in water is glucose

When comparing hydrochloric acid (HCl) and ethyl chloride (CH3CH2Cl), the one that is more soluble in water is hydrochloric acid

Explanation:

When comparing propionic acid (CH₃CH₂COOH) and sodium propionate (CH₃CH₂COONa), the one that is more soluble in water sodium propionate. Because always a salt is more soluble in water than its acid (Solubility of propionic acid is 0,37g/mL and of sodium propionate is 1g/mL).

When comparing cyclohexane (C6H12) and glucose (C6H12O6), the one that is more soluble in water is glucose because cyclohexane is made from petroleum and its polarity is very low (cyclohexane is insoluble in water and solubility of glucose is 0,91g/mL).

When comparing hydrochloric acid (HCl) and ethyl chloride (CH3CH2Cl), the one that is more soluble in water is hydrochloric acid because an acid has a medium-high solubility in water but, again, an alkane derived from petroleum has very low solubility in water (hydrochloric acid has a solubility of 0,823g/mL and ethyl chloride is insoluble in water).

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Chemistry
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P Answered by Specialist

When comparing propionic acid (CH₃CH₂COOH) and sodium propionate (CH₃CH₂COONa), the one that is more soluble in water sodium propionate.

When comparing cyclohexane (C6H12) and glucose (C6H12O6), the one that is more soluble in water is glucose

When comparing hydrochloric acid (HCl) and ethyl chloride (CH3CH2Cl), the one that is more soluble in water is hydrochloric acid

Explanation:

When comparing propionic acid (CH₃CH₂COOH) and sodium propionate (CH₃CH₂COONa), the one that is more soluble in water sodium propionate. Because always a salt is more soluble in water than its acid (Solubility of propionic acid is 0,37g/mL and of sodium propionate is 1g/mL).

When comparing cyclohexane (C6H12) and glucose (C6H12O6), the one that is more soluble in water is glucose because cyclohexane is made from petroleum and its polarity is very low (cyclohexane is insoluble in water and solubility of glucose is 0,91g/mL).

When comparing hydrochloric acid (HCl) and ethyl chloride (CH3CH2Cl), the one that is more soluble in water is hydrochloric acid because an acid has a medium-high solubility in water but, again, an alkane derived from petroleum has very low solubility in water (hydrochloric acid has a solubility of 0,823g/mL and ethyl chloride is insoluble in water).

I hope it helps!

Chemistry
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P Answered by Specialist

Answer : The pH of the solution is, 4.25

Solution :  Given,

Concentration (C) = 3.010\times 10^{-4}M

Acid dissociation constant = k_a=1.310\times 10^{-5}

The equilibrium reaction for dissociation of C_2H_5CO_2H (weak acid) is,

                           C_2H_5CO_2H\rightleftharpoons C_2H_5CO_2^-+H^+

initially conc.        c                       0                0

At eqm.             c(1-\alpha)                c\alpha                c\alpha

where, \alpha is degree of dissociation

First we have to calculate the value of \alpha

K_a=\frac{(c\alpha)\times (c\alpha)}{c(1-\alpha)}

K_a=\frac{c(\alpha)^2}{(1-\alpha)}

Now put all the given values in this formula, we get:

1.310\times 10^{-5}=\frac{(3.010\times 10^{-4})(\alpha)^2}{(1-\alpha)}

\alpha=0.188

Now we have to calculate the hydrogen ion concentration.

[H^+]=c\alpha=(3.010\times 10^{-4})\times (0.188)=5.66\times 10^{-5}M

Now we have to calculate the pH.

pH=-\log [H^+]

pH=-\log (5.66\times 10^{-5})

pH=4.25

Therefore, the pH of the solution is, 4.25

Chemistry
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The pH of the buffer after addition of given amount of HI is 4.76

Explanation:

We are given:

Initial moles of propionic acid = 0.17 moles

Initial moles of sodium propionate = 0.14 moles

Moles of HI added = 0.01 moles

The chemical equation for the reaction of HI and sodium propionate follows:

                      C_2H_5COONa+HI\rightleftharpoons C_2H_5COOH+NaI

Initial:                      0.14            0.01         0.17

At eqllm:                 0.13               -            0.18

Total volume of the container = 1.20 L

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

pH=pK_a+\log(\frac{[salt]}{[acid]})

pH=pK_a+\log(\frac{[C_2H_5COONa]}{[C_2H_5COOH]})

We are given:  

pK_a = negative logarithm of acid dissociation constant of propionic acid = 4.87

[C_2H_5COONa]=\frac{0.14}{1.20}

[C_2H_5COOH]=\frac{0.18}{1.20}

pH = ?

Putting values in above equation, we get:

pH=4.87+\log(\frac{0.14/1.20}{0.18/1.20})\\\\pH=4.76

Hence, the pH of the buffer after addition of given amount of HI is 4.76

Chemistry
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P Answered by Specialist

The pH of acid solution is 4.58

Explanation:

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in mL)}}    .....(1)

For KOH:

Molarity of KOH solution = 1.1000 M

Volume of solution = 41.04 mL

Putting values in equation 1, we get:

1.1000M=\frac{\text{Moles of KOH}\times 1000}{41.04}\\\\\text{Moles of KOH}=\frac{1.1000\times 41.04}{1000}=0.04514mol

For propanoic acid:

Molarity of propanoic acid solution = 0.6100 M

Volume of solution = 224.9 mL

Putting values in equation 1, we get:

0.6100M=\frac{\text{Moles of propanoic acid}\times 1000}{224.9}\\\\\text{Moles of propanoic acid}=\frac{0.6100\times 224.9}{1000}=0.1372mol

The chemical reaction for propanoic acid and KOH follows the equation:

                 C_2H_5COOH+KOH\rightarrow C_2H_5COOK+H_2O

Initial:          0.1372         0.04514  

Final:           0.09206          -                0.04514

Total volume of solution = [224.9 + 41.04] mL = 265.94 mL = 0.26594 L     (Conversion factor:  1 L = 1000 mL)

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

pH=pK_a+\log(\frac{[\text{salt}]}{[acid]})

pH=pK_a+\log(\frac{[C_2H_5COOK]}{[C_2H_5COOH]})

We are given:  

pK_a = negative logarithm of acid dissociation constant of propanoic acid = 4.89

[C_2H_5COOK]=\frac{0.04514}{0.26594}

[C_2H_5COOH]=\frac{0.09206}{0.26594}

pH = ?  

Putting values in above equation, we get:

pH=4.89+\log(\frac{(0.04514/0.26594)}{(0.09206/0.26594)})\\\\pH=4.58

Hence, the pH of acid solution is 4.58

Chemistry
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P Answered by Specialist

The activation energy is 164.02 kJ/mol

Explanation:

Log (k2/k1) = Ea/2.303R × [1/T1 - 1/T2]

k1 = 8.9×10^-4 s^-1

k2 = 9.83×10^-3 s^-1

R = 8.314 J/mol.K

T1 = 540 K

T2 = 578 K

Log (9.83×10^-3/8.9×10^-4) = Ea/2.303×8.314 × [1/540 - 1/578]

1.043 = 6.359×10^-6Ea

Ea = 1.043/6.359×10^-6 = 164020 J/mol = 164020/1000 = 164.02 kJ/mol

Chemistry
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P Answered by PhD

C) k_a=1.3\times 10^{-5}

Explanation:

pH is defined as the negative logarithm of the concentration of hydrogen ions.

Thus,  

pH = - log [H⁺]

The expression of the pH of the calculation of weak acid is:-

pH=-log(\sqrt{k_a\times C})

Where, C is the concentration = 0.5 M

Given, pH = 2.94

Moles = 0.100 moles

Volume = 1.00 L

So, Molarity=\frac{Moles}{Volume}=\frac{0.100}{1.00}\ M=0.100\ M

C = 0.100 M

2.94=-log(\sqrt{k_a\times 0.100})

\log _{10}\left(\sqrt{k_a0.1}\right)=-2.94

\sqrt{0.1}\sqrt{k_a}=\frac{1}{10^{2.94}}

k_a=1.3\times 10^{-5}

Chemistry
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P Answered by Master

Explanation:

It is known that pK_{a} of propionic acid = 4.87

And, initial concentration of  propionic acid = \frac{0.19}{1.20}

                                                                       = 0.158 M

Concentration of sodium propionate = \frac{0.26}{1.20}[/tex]

                                                             = 0.216 M

Now, in the given situation only propionic acid and sodium propionate are present .

Hence,      pH = pK_{a} + log(\frac{[salt]}{[acid]})

                       = 4.87 + log \frac{0.216}{0.158}

                        = 4.87 + log (1.36)

                        = 5.00

Therefore, when 0.02 mol NaOH is added  then,

     Moles of propionic acid = 0.19 - 0.02

                                              = 0.17 mol

Hence, concentration of propionic acid = \frac{0.17}{1.20 L}

                                                                 = 0.14 M

and,      moles of sodium propionic acid = (0.26 + 0.02) mol

                                                                  = 0.28 mol

Hence, concentration of sodium propionic acid will be calculated as follows.

                        \frac{0.28 mol}{1.20 L}

                           = 0.23 M

Therefore, calculate the pH upon addition of 0.02 mol of NaOH as follows.

             pH = pK_{a} + log(\frac{[salt]}{[acid]})

                       = 4.87 + log \frac{0.23}{0.14}

                        = 4.87 + log (1.64)

                        = 5.08

Hence, the pH of the buffer after the addition of 0.02 mol of NaOH is 5.08.

Therefore, when 0.02 mol HI is added  then,

     Moles of propionic acid = 0.19 + 0.02

                                              = 0.21 mol

Hence, concentration of propionic acid = \frac{0.21}{1.20 L}

                                                                 = 0.175 M

and,      moles of sodium propionic acid = (0.26 - 0.02) mol

                                                                  = 0.24 mol

Hence, concentration of sodium propionic acid will be calculated as follows.

                        \frac{0.24 mol}{1.20 L}

                           = 0.2 M

Therefore, calculate pH upon addition of 0.02 mol of HI as follows.

             pH = pK_{a} + log(\frac{[salt]}{[acid]})

                       = 4.87 + log \frac{0.2}{0.175}

                        = 4.87 + log (0.114)

                        = 4.98

Hence, the pH of the buffer after the addition of 0.02 mol of HI is 4.98.

Chemistry
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P Answered by Specialist

Concentration of hydroxide-ion at equivalence point = 8.3\times 10^{-6}M

Explanation:

HC_{3}H_{5}O_{2}+KOH\rightarrow C_{3}H_{5}O_{2}^{-}K^{+}+H_{2}O

1 mol of HC_{3}H_{5}O_{2} reacts with 1 mol of KOH to produce 1 mol of C_{3}H_{5}O_{2}^{-}

At equivalence point, all HC_{3}H_{5}O_{2} gets converted to C_{3}H_{5}O_{2}^{-}.

Moles of C_{3}H_{5}O_{2}^{-} produced at equivalence point is equal to moles of KOH added to reach equivalence point.

So, moles of C_{3}H_{5}O_{2}^{-} produced = \frac{43.76\times 0.141}{1000}moles=0.00617moles

Total volume of solution at equivalence point = (25.00+43.76) mL = 68.76 mL

Concentration of C_{3}H_{5}O_{2}^{-} at equivalence point = \frac{0.00617\times 1000}{68.76}M=0.0897M

OH^{-} produced at equivalence point is due to hydrolysis of C_{3}H_{5}O_{2}^{-}. We have to construct an ICE table to calculate concentration of OH^{-} at equivalence point.

C_{3}H_{5}O_{}^{-}+H_{2}O\rightleftharpoons HC_{3}H_{5}O_{2}+OH^{-}

I:0.0897                               0                    0

C: -x                                     +x                   +x

E: 0.0897-x                          x                      x

\frac{[HC_{3}H_{5}O_{2}][OH^{-}]}{[C_{3}H_{5}O_{2}^{-}]}=K_{b}(C_{3}H_{5}O_{2}^{-})=\frac{10^{-14}}{K_{a}(HC_{3}H_{5}O_{2})}

species inside third bracket represent equilibrium concentrations

So, \frac{x^{2}}{0.0897-x}=7.69\times 10^{-10}

or, x^{2}+(7.69\times 10^{-10}\times x)-(6.90\times 10^{-11})=0

So, x=\frac{-(7.69\times 10^{-10})+\sqrt{(7.69\times 10^{-10})^{2}+(4\times 6.90\times 10^{-11})}}{2}M = 8.3\times 10^{-6}M

So, concentration of hydroxide-ion at equivalence point = x M =  8.3\times 10^{-6}M

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